Richard, Thank you for sharing your results! As you surmised and Figaro pointed out, the mineral/ionic composition of the 2 water sources are likely to be different. Associated with a potential pH difference that Figaro notes, your city water may be seriously alkaline. A terrific explanation of those 2 factors is in the attached pdf. A high pH with low alkalinity is not so bad. High pH with high alkalinity is another matter. If you want to test the alkalinity yourself, a good, accurate, easy to use & fairly cheap test kit is:
http://www.hach.com/alkalinity-test-kit-model-al-ap/product?id=7640220951&callback=bc
However, your water provider tests for all those things plus more. They know the pH, alkalinity, mineral composition, microbiological composition, etc. You can call them and request their test results. Whether they will tell you is another matter entirely. Some water service companies will and some will not. It is worth a phone call or two. If they do share, adding that info to this thread would be helpful I think.
Thank you again for reminding the forum that water quality makes a real difference!