I have been using it. I add about a cup when I prepare a new batch of potting mix. I'm not sure how much it helps but my trees are all happy, of course I add a good deal of other things as well.
I have read a little more on it in the last couple days since Daniel/ediblelandscapingsc commented(not his exact words here, just the jist) he doesn't use it because of some possibly harmful contents. So I searched "Azomite harmful" and "Azomite risks" and read for a while. The radiation aspect was what I was most interested in. Azomite does primarily come from the earths magma core so most if not every element on earth is present..and the earth's core is sort of like a huge reactor so naturally there is remnant radiation. But, we evolved with that radiation present all over the earth so I'm not sure it is a issue. The radiation from man's experiments and mistakes, that is a different can of worms. I will probably end up doing more reading on the subject, problem is there are no real studies just a good deal of theory and opinion on the matter.