Check with farm supply stores. I buy lime by the ton. I also pore cement in several states the raw materials vary. They are made from limestone, granite, Sand, river rock, and Portland cement. Portland Cement would be the ingredient you are looking for but is much more expensive than raw lime. I'm sure I would prefer buying lime or hydrated lime in stead of concrete. I would check my ph to see how much lime I needed. IMHO there are more benefits to planting near concrete than the lime, nematode reduction, moisture, fewer plant root or chemical warfare from plants pressure ,equal to a herbicide strip. Mulching a large area would probably be more beneficial than using concrete or Portland cement. I'm sure someone could explained it much better than I can. If you already have areas with concrete by all means use them. Like FMD receives benefit with the Alma sisters but it's not just the concrete that releases lime that benefits the trees. There are many other things that play in to it.