Fig trees like slightly acidic soils ( 6 to 6.5), but fig trees cannot tolerate low pH
Fig's nutrition indicated that it needs Calcium and Magnesium.
Limestone has both, it does PH balancing, It means that it will keep PH = 7 at neutral slowly, at the same time, It releases Calcium and Magnesium.
Rainfall is acidic.
Peat moss, pine needles, pine bark mulch/fine are acidic.
Of course, If your coffee ground is acidic, you can use it too.
The tricky part is that, how do you mix them up for best results.