I have decided to contribute although as I get older, I realize I am almost never right about anything.
Bicarbonate of Soda and Baking Soda are different names for the same thing. They have a PH level of "ABOUT" 9. I have not tried this on figs, but the reason they should work is by changing the PH level of the mold growing on the cuttings. I have noticed that mold ("powdery mildew") on roses, can be pretty much eliminated by spraying with a mixture of Baking Soda and water (raising the PH), or by spraying with a mixture of Vinegar and water (lowering the PH). Either one seems to work.
I believe that Frank is also correct as fresh air circulation seems to prevent molds.
I am afraid of bleach as I once killed a number of Iris rhizomes by soaking them for too long in a bleach solution. Entirely my fault, but I still refuse to take the blame. Done correctly, it should work (I think).
As with anything I say, verify this for yourself. I hate to think about all the plants I've killed, thinking I knew what I was doing.
John