There doesn’t seem to be consensus on if spent coffee grounds actually influence soil ph. There is a school of thought that suggests all (or most) the acidity winds up in the cup of coffee and not in the spent grounds.
There also doesn’t appear to be any formal guidelines on how much to apply, how often, etc. to get an expected result.
Unless you’re ready to test different application rates, monitor the results and adjust accordingly, I would suggest relying on the sulfur approach as Ross suggested above.