HI,
You don't need to peel, but scratching the skin will help. Just take a blade and brush against the stem. You don't have to go deep, just stay at surface level.
I did it this year.
The results were better than last year - chance or not ... for this time at least it was so.
I never use any rooting compound. You really don't need that for fig trees, except perhaps if you reallllllllllllllllllllllllllllly want to be sure to have success.
I airlayered Panaché, Osborn prolific this year and both rooted in time. I did that in mid-august, so time was running short, thus my scratchings on the stems.
I did the same for my healthy longue d'aout, but I didn't get enough roots - or any roots. I just left everything on place. I'll check by next Spring if it is rooted ...
There might have been one or two tiny roots, but for fear for breaking them, I didn't investigate further.